Phosphate hideout in boilers
WebAcid Phosphate Corrosion occurs where high levels of deposits are present and an acidic phosphate compound is used as part of the boiler water or evaporator water treatment program. Poor feedwater treatment often results in high corrosion product levels. WebThe following conditions appear to be necessary for this type of cracking to occur : 1. The metal must be stressed, 2. the boiler-water must contain caustic, 3. at least a trace of silica must be present in the boiler-water, and. 4. some mechanisms, such as a slight leak, must be present to allow the boiler water to concentrate on the stressed ...
Phosphate hideout in boilers
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WebMar 15, 2015 · Phosphate hideout is characterized by the retention of phosphate in the boiler during conditions of high pressure and the subsequent release of phosphate when the pressure is reduced. The condition is most often reported in high-pressure units, e.g., 2,500 psi (17.24 MPa). WebMar 22, 2009 · Many U.S. electric utilities have converted their drum boilers to caustic treatment and eliminated problems such as phosphate hideout. This paper will discuss the basics of caustic treatment and present some case histories of successful operation in a caustic boiler water treatment regimen.
WebPhosphate hideout is a phenom- enon that causes boiler water control difficulties. It is defined as the disappearance, by precipita- tion or absorption, of the ionic phosphate (PO4) species, in the boiler water under high heat transfer or high load conditions. When the high heat flux or high load condition is reduced, the WebUsually associated with low pH excursions Formation of nascent hydrogen (HO) at the boiler tube surface Hydrogen permeates the tube where it can react with Iron carbides to form methane gas Other hydrogen atoms to form hydrogen gas Gases collect at grain boundaries to increase pressure Microfissures occur within the material and weaken the tube
WebMar 15, 2015 · Phosphate hideout is characterized by the retention of phosphate in the boiler during conditions of high pressure and the subsequent release of phosphate when … WebJan 4, 2010 · Phosphate Hideout Because the solubility of phosphate decreases as boiler pressure increases, hideout is typically only noticed during load changes. Phosphate hideout usually ... boiler water phosphate residual that accompanies this solid phase formation problem. The phosphate hideout phenomenon can pose a significant chemistry ...
WebThe minimum phosphate is 0.2 mg/L. PC(L) or Phosphate Continuum (Low) requires higher purity feedwater, but uses lower phosphate target ranges and minimizes the propensity for phosphate hideout. PC(H) or Phosphate Continuum (High) is the most forgiving program if there are upsets in boiler feedwater quality, but it does increase the propensity ...
http://www.steamcycle.com/hideout.htm irish news health and lifestylehttp://www.steamcycle.com/hideout.htm irish news high flyersWebAll the hidden out phosphate will come back into the soluble form in the boiler drum water. Analyze residual phosphate in the boiler drum water. When the residual phosphate is … irish news headlines dublinWebAnother significant function of trisodium phosphate added to boiler water is to combine with suspended calcium and magnesium cations in order to minimize susceptibility to deposit … port authority bus schedule g2WebPhosphate hideout usually results in an increase of PO4 concentration and a decrease of pH during load reduction and in an increase of pH and decrease of PO4 concentration during the load increases. The severity of phosphate hideout is boiler, heat flux, temperature, pressure, and boiler cleanliness specific. port authority budget toteWebnoncontact cooling, and boiler blowdown wastewater) •Does not contain a substance regulated by 360 CMR 10.022 through 10.024; •Avg < than 300 gallons per day of … port authority bus schedules pittsburgh paWebThe observations from this study suggested a maximum desirable range for Na/PO 4 molar ratio in solution of 2.2 to 2.6 for phosphate treatment of steam generator water. Lithium phosphate treatment is unsuitable because it forms hard scales and also causes accelerated corrosion of boiler tubing. port authority bus schedule to toms river