WebIron-catalyzed reductive strecker reaction. Strecker reaction is widely applied for the synthesis of amino acids from aldehydes, amines and cyanides. Herein, we report the … WebSep 1, 2024 · Iridium-catalyzed reductive Strecker reaction for late-stage amide and lactam cyanation. Angew. Chem. Int. Ed., 56 (2024), pp. 3655-3659. CrossRef View in Scopus Google Scholar. 9. L.-G. Xie, D.J. Dixon. Tertiary amine synthesis via reductive coupling of amides with Grignard reagents.
Iron-catalyzed reductive strecker reaction ScienceGate
WebFeb 24, 2024 · A new iridium-catalyzed reductive Strecker reaction for the direct and efficient formation of α-amino nitrile products from a broad range of (hetero)aromatic and aliphatic tertiary amides, and N-alkyl lactams is reported. WebApr 8, 2024 · Iron catalysis has seen an impressive breakthrough during the last two decades, and iron can now be considered as a valuable alternative transition metal for … ipod flash drive
Rhodium(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic …
WebAsymmetric Strecker reactions. Asymmetric Strecker reactions are well developed. By replacing ammonia with (S)-alpha-phenylethylamine as chiral auxiliary the ultimate … WebDec 5, 2024 · At the outset of investigation, various reaction parameters were established for the Zr(IV)–H-catalyzed transamination of napropamide with n-propyl amine in the presence of PhSiH 3 as a hydride reductant (Table 1).Similar to the case of using Schwartz’s reagent, the combination of inexpensive Cp 2 ZrCl 2 and NaOMe, which act as the pre … WebOct 28, 2024 · With the optimized reaction conditions for the electrooxidative iron-catalyzed C−H arylation being identified, we next probed its robustness with a representative set of benzamides 1 (Scheme 1 a). Differently N-substituted triazoles 1 were selectively converted into the desired products. ipod first generation battery